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2.2]decane core and defining the geometry of the exocyclic double bond. The activation energies of development of your vinyl-gold intermediates were being calculated and disclosed a silyl enol ether by having an unprotected indole moiety as an appropriate precursor for that Toste cyclization. This six-move synthesis did not include any nonstrategic
2.two]decane core and defining the geometry of the exocyclic double bond. The activation energies of formation from the vinyl-gold intermediates were calculated and disclosed a silyl enol ether with the unprotected indole moiety as an appropriate precursor with the Toste cyclization. This six-move synthesis didn't include any nonstrategic redox man